Cellulose derivative spinning solution containing wax



Patented June 29, 1937 Parser easier.

CELLULOSE DERIVATIVE SPINNING SOLU- TION CONTAINING WAX Camille Dreyfus, New York, N. Y., and William Whitehead, Cumberland, Md., assignors to Gelanese Corporation of America, a corporation of Delaware No Drawing. Original application November 10,

1928, Serial No. 318,583. Divided and this application October 6,

8 Claims.

This invention relates to the manufacture of films or filaments, such as artificial yarns, fibers, bristles, straw, ribbons and the like, from solutions containing organic derivatives of cellulose.

This application is a division of our application S. No. 318,583 filed November 10, 1928.

An object of our invention is to preparefilaments or films containing organic derivatives of cellulose that are tougher and more pliable than 10 those heretofore made.

Another object of our invention is to form films or filaments containing organic derivatives of cellulose from solution containing a wax as a nonsolvent or precipitant for the organic derivatives of cellulose.

Another object of our invention is to form films or filaments containing organic derivatives of cellulose that become delustered readily. Gther objects of our invention will appear from the following detailed description.

Artificial filaments containing organic derivatives of cellulose have been prepared formerly by extrusion of solutions of the derivatives of cellulose in a volatile solvent through the orifices of a spinnerette into an evaporative atmosphere. Yarns made from such filaments are not as tough and pliable as may be desirable, and therefore the amount of twist that may be imparted to them, or the closeness with which such yarns may be knitted, is limited, since if a predetermined limit is exceeded, the same tend to break or become materially weakened. Moreover such prior yarns or fabrics made from such yarns, become delustered in dyeing or scouring baths only at temperatures approaching that of boiling water, unless other delustering agents have been employed in the bath. We have found that if waxes that are non-solvents or precipitants for the organic derivatives of cellulose are added to the spinning solution containing the same, filaments may be formed that are tougher and more pliable, and also in some instances more readily delustered, than those made by the prior processes. Yarns made from such filaments, among other desirable properties, may have a much higher twist safely imparted thereto, they may be safely knitted closely on a circular knitting machine and may, in some instances, be delustered in dyeing or scouring baths, at much lower temperatures than yarns made by the prior processes.

In accordance with our invention, we prepare filaments or films from solutions containing organic derivatives of cellulose in a suitable solvent, in which solution there has been incorporated,

1933, Serial No. 692,428

either by solution or emulsification, a wax that is a non-solvent or a precipitant for the organic derivatives of cellulose. The solution so formed, preferably after thorough mixing to obtain uniformity, may be filtered and then extruded through orifices of required size of a spinnerette either into a drying or evaporative atmosphere, as in dry spinning, or into a precipitating bath containing liquid such as water, kerosene, etc., as in wet spinning.

The filaments that may be formed by our invention may be the fine filaments having a denier of say 1 to 10 such as used for making yarns, or they may be much heavier having a denier of say 50 to 2000 denier to be used as artificial bristles for making brushes or for making artificial furs, etc. Our invention may also be advantageously employed for making tough and pliable films for photographic purposes or other purposes, for making plastics, etc., where pliability is required.

Any suitable organic derivatives of cellulose may be used in our invention. These may be organic esters of cellulose such as cellulose acetate, cellulose formate, cellulose propionate and cellulose butyrate, or cellulose ethers such as ethyl cellulose, methyl cellulose and benzyl cellulose. This invention is particularly applicable in connection with acetone soluble cellulose acetate having acetyl values of around 54% (determined as acetic acid).

Any suitable solvent may be employed for making the solution of the organic derivatives of cellulose. Examples of such solvents are acetone, acetone and ethyl or methyl alcohol, chloroform, ethylene dichloride, ethylene dichloride and ethyl or methyl alcohol, methylene chloride and ethyl or methyl alcohol, etc.

Any suitable wax that is a non-solvent or precipitant for organic derivatives of cellulose may be added to the solution of the same in accordance with our invention. Examples of such waxes are paraffin wax, carnauba wax, spermacetti, etc. Mixtures of two or more of these waxes may be employed, and these may or may not be miscible with each other.

It is advisable either to mix the wax with the solution of the derivative of cellulose at a temperature high enough to melt such wax; or else first to dissolve the wax in a small quantity of a solvent for the same, such as benzene, and add the solution so formed to the solution of the organic derivative of cellulose. The solution of the wax should preferably be added slowly to permit the wax which precipitates from its solution in the solvent employed for dissolving the organic derivative of cellulose, to become thor oughly disseminated or emulsified in colloidal form if necessary in the solution of the organic derivative of cellulose.

While we have found that the addition of even small quantities of waxes to the spinning solution improves the properties of the filaments formed, we find that the maximum benefit is derived when amounts of wax equal to 2.5 to 10% or more of the weight of the derivative of cellulose present are added to the spinning solution.

The luster of the films, filaments or yarns produced by our method may be readily subdued in some instances depending upon the amount and nature of the wax added to the spinning solution. Thus, if a certain quantity of wax based on the weight of the cellulose acetate present in the spinning solution is added, yarns formed from the same will deluster appreciably when subjected to water at C. If only one-half of this amount of wax is added, the resultant yarn is delustered to a considerably less extent when treated with water under similar conditions. Thus, by controlling the amount of Wax added, the delustering properties of the yarn may be controlled.

Filaments, yarns or films formed by our invention are tough and pliable, which is surprising since this would not be expected in theory. Thus, yarns made from our filaments may have a twist imparted thereto having 30 or 40% more turns per unit length than may the prior yarns, without reaching the weakening point. Yarns formed by our invention may be knitted 30% or more closer than yarns made by the prior process; that is, a circular knitted or warp knitted fabric may be formed having 30% more wales, courses or stitches than fabrics made from prior yarns. Yarns or bristles made by our process may be formed into stronger knots, while artificial straws or ribbons or the like made by our process have improved plaiting qualities and may be subjected to considerably more sever processing.

When wax is added to the spinning solution it might not always be entirely removed from the yarns or fabrics by the ordinary scouring method. Despite this fact, such yarns or fabrics may be subjected to such treatments as saponification, dyeing with vat dyes, basic dyes, or water insoluble dyes dispersed in colloidal solution, by normal methods with normal results.

It is to be understood that the foregoing detailed description is given merely by way of illustration and that many variations may be made therein without departing from the spirit of our invention.

Having described our invention what we claim and desire to secure by Letters Patent is:

1. Method of forming a spinning solution for the production of artificial materials of improved properties, which comprises dissolving a derivative of cellulose selected from the group consisting of organic acid esters of cellulose and cellulose ethers in a solvent and mixing a wax with the said derivative of cellulose solution at a temperature high enough to melt the wax.

2. Method of forming a spinning solution for the production of artificial materials of improved properties, which comprises dissolving an acetone-soluble cellulose acetate in a solvent and mixing a wax with the said solution at a temperature high enough to melt the wax.

3. Method of forming a spinning solution for the production of artificial materials of improved properties, which comprises dissolving a derivative of cellulose selected from the group consisting of organic acid esters of cellulose and cellulose ethers in a solvent and mixing a wax, in an amount equal to 2.5 to 10 per cent based on the weight of the derivative of cellulose present, with the said derivative of cellulose solution at a temperature high enough to melt the wax.

4. Method of forming a spinning solution for the production of artificial materials of improved properties, which comprises dissolving an acetone-soluble cellulose acetate in a solvent and mixing a wax, in an amount equal to 2.5 to 10 per cent based on the weight of the cellulose acetate present, with the said solution at a temperature high enough to melt the wax.

5. A spinning solution for use in the production of artificial materials of improved properties, comprising a derivative of cellulose selected from the group consisting of organic acid esters of cellulose and cellulose ethers dissolved in a volatile solvent therefor and melted wax.

6. A spinning solution for use in the production of artificial materials of improved properties, comprising acetone-soluble cellulose acetate dissolved in a volatile solvent therefor and melted wax.

7. A spinning solution for use in the production of artificial materials of improved properties, comprising a derivative of cellulose selected from the group consisting of organic acid esters of cellulose and cellulose ethers dissolved in a volatile solvent therefor and melted wax in an amount equal to 2.5 to 10 per cent based on the weight of the derivative of cellulose present.

8. A spinning solution for use in the production of artificial materials of improved properties, comprising acetone-soluble cellulose acetate dissolved in a volatile solvent therefor and melted wax in an amount equal to 2.5 to 10 per cent based on the weight of the cellulose acetate present.

CAMILLE DREYFUS. WILLIAM WHITEHEAD. 

